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Symmetric Stretching Mode:

The molecule is alternately stretched and compressed, both C-O bonds changing simultaneously as in figure.

Figure: The symmetric stretching vibration of the carbon dioxide molecule
\begin{figure}\centerline{\hbox{\psfig{file=symm.ps,width=0.5\textwidth}}}\end{figure}

Plainly the dipole moment remains zero throughout the whole of this motion, and this particular vibration is 'infrared inactive'. The frequency of this mode is

$\displaystyle \nu_1$ $\displaystyle =$ $\displaystyle 3.99 \times 10^{13} s^{-1}$  
  $\displaystyle =$ $\displaystyle 1330 cm^{-1}$  

The associated quantum number is denoted by $ v_1$.



Ms Rajwinder Kaur 2004-11-11